SOLVENT EFFECTS ON THE STEREOSELECTIVITY OF KETENE-IMINE CYCLOADDITION REACTIONS

Authors
LOPEZ R SUAREZ D RUIZLOPEZ MF GONZALEZ J SORDO JA SORDO TL
Citation
R. Lopez et al., SOLVENT EFFECTS ON THE STEREOSELECTIVITY OF KETENE-IMINE CYCLOADDITION REACTIONS, Journal of the Chemical Society, Chemical Communications, (16), 1995, pp. 1677-1678
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Journal of the Chemical Society, Chemical Communications → ACNP
ISSN journal
00224936
Issue
16
Year of publication
1995
Pages
1677 - 1678
Database
ISI
SICI code
0022-4936(1995):16<1677:SEOTSO>2.0.ZU;2-0
Abstract
According to ab initio computations, the electrostatic solute-solvent interactions are predicted to be critical in the control of the stereo selectivity of the [2 + 2] ketene-imine cycloaddition reactions caused by the torquoelectronic effect.