HOST-GUEST INTERACTIONS IN PURE-SILICA AND ALUMINOSILICATE SODALITES CONTAINING ETHYLENE-GLYCOL AS A GUEST MOLECULE

Four sodalite materials with Si/Al ratios of infinity, 23.0, 11.0, and 5.7 are synthesized from essentially nonaqueous media in which ethyle ne glycol is acting both as a solvent and as a structure-directing age nt. Elemental and thermal analyses, X-ray powder diffraction, multinuc lear MAS NMR, and vibrational spectroscopies are employed to extensive ly investigate the host-guest interactions in as-synthesized materials . It is found that the hydrogen-bonding feature of the ethylene glycol molecules encapsulated within the P-cages of sodalites is strongly af fected by the Al content in the framework. The overall results of this study lead us to conclude that the molecular conformation of ethylene glycol in the pure-silica beta-cage may be tGg' stabilized only by on e intramolecular hydrogen bond, while that of the guest molecule in th e beta-cage with a Si/Al ratio of 5 is gGg' stabilized by one strong h ydrogen bond to ; the framework in addition to one intramolecular hydr ogen bond.