EFFECT OF TETRAALKYLAMMONIUM SALTS ON THE CATHODIC EVOLUTION OF HYDROGEN IN CONCENTRATED ACIDIC BROMIDE SOLUTIONS

Authors
PLETNEV MA SHIROBOKOV IB OVECHKINA OE RESHETNIKOV SM
Citation
Ma. Pletnev et al., EFFECT OF TETRAALKYLAMMONIUM SALTS ON THE CATHODIC EVOLUTION OF HYDROGEN IN CONCENTRATED ACIDIC BROMIDE SOLUTIONS, Protection of metals, 31(4), 1995, pp. 317-320
Citations number
21
Categorie Soggetti
Metallurgy & Metallurigical Engineering
Journal title
Protection of metals → ACNP
ISSN journal
00331732
Volume
31
Issue
4
Year of publication
1995
Pages
317 - 320
Database
ISI
SICI code
0033-1732(1995)31:4<317:EOTSOT>2.0.ZU;2-D
Abstract
The effect of inorganic K+ and organic tetraethyl- (TEA(+)) and tetrab utylammonium (TBA(+)) bromides on the cathodic evolution of hydrogen i n concentrated acidic bromide solutions was studied experimentally. Th e effect of tetraalkylammonium cations on the rate of hydrogen evoluti on in acidic bromide solutions was shown to result from a change in th e structure of water in the adsorption layer.