The X-ray diffraction, atomic force microscopic (AFM) and X-ray photoe
lectron spectroscopic (XPS) measurements are reported for the Orissa g
emstone confirming it to be sillimanite. A comparison beween sillimani
te and the so-called moonstone from Orissa (K-feldspar) has also been
made. Our X-ray diffraction and XPS measurements resolve the question
of identification of the two gemstones beyond any doubt.