SELF REPRODUCTION OF CHIRALITY IN PYROGLUTAMATES - REACTIONS AT ALPHA-POSITION WITH ELECTROPHILES

Authors
DIKSHIT DK MAHESHWARI A PANDAY SK
Citation
Dk. Dikshit et al., SELF REPRODUCTION OF CHIRALITY IN PYROGLUTAMATES - REACTIONS AT ALPHA-POSITION WITH ELECTROPHILES, Tetrahedron letters, 36(34), 1995, pp. 6131-6134
Citations number
23
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
34
Year of publication
1995
Pages
6131 - 6134
Database
ISI
SICI code
0040-4039(1995)36:34<6131:SROCIP>2.0.ZU;2-Q
Abstract
Condensation of pyroglutamic acid with trimethylacetaldehyde gave a bi cyclic derivative which on deprotonation with LiHMDS and reaction with electrophiles gives chiral cl-substituted pyroglutamate derivatives.