ENHANCING THE SENSITIVITY OF CHEMICAL SENSORS FOR CHLORINATED HYDROCARBONS IN WATER BY THE USE OF TAPERED SILVER-HALIDE FIBERS AND TUNABLE DIODE-LASERS
R. Gobel et al., ENHANCING THE SENSITIVITY OF CHEMICAL SENSORS FOR CHLORINATED HYDROCARBONS IN WATER BY THE USE OF TAPERED SILVER-HALIDE FIBERS AND TUNABLE DIODE-LASERS, Applied spectroscopy, 49(8), 1995, pp. 1174-1177
Tapered silver halide fibers were used for the first time for high-sen
sitivity fiber evanescent wave spectroscopic (FEWS) measurements of ch
lorinated hydrocarbons (CHCs) in water at trace level. The sensor arra
ngement consisted of a tunable diode laser (TDL) source, a polymer-coa
ted and tapered silver halide fiber, and a direct fiber/mercury cadmiu
m telluride (MCT) detector coupling. A minimum detection limit of 50 m
u g L(-1) was achieved by using a polyisobutylene-coated fiber with a
1:4 tapering ratio. The sensor response is in the minute range and sho
ws reversible analyte enrichment.