DIRECT ANODIC-OXIDATION OF P-METHOXYTOLUENE IN METHANOL - THE EFFECT OF ELECTROLYSIS CONDITIONS

Authors
OGIBIN YN ILOVAISKY AI MERKULOVA VM NIKISHIN GI
Citation
Yn. Ogibin et al., DIRECT ANODIC-OXIDATION OF P-METHOXYTOLUENE IN METHANOL - THE EFFECT OF ELECTROLYSIS CONDITIONS, Russian chemical bulletin, 44(3), 1995, pp. 507-510
Citations number
11
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
3
Year of publication
1995
Pages
507 - 510
Database
ISI
SICI code
1066-5285(1995)44:3<507:DAOPIM>2.0.ZU;2-I
Abstract
The effect of anions of the supporting electrolyte (F-, dialkylphospha te, TsO(-), and BF4-) and other electrolysis conditions (anode materia l, temperature, substrate concentration) on the selectivity of the dir ect anodic oxidation of p-methoxytoluene in methanol into 4-methoxy-be nzaldehyde dimethylacetal was studied. The highest selectivity was obt ained in the presence of fluoride anion.