ENTHALPIES OF SOLUTION AND CRYSTALLIZATION OF AMMONIUM ALUMINUM SULFATE DODECAHYDRATE IN WATER AT 25-DEGREES-C

Authors
FISHER J PEKAREK V WOLF G NYVLT J
Citation
J. Fisher et al., ENTHALPIES OF SOLUTION AND CRYSTALLIZATION OF AMMONIUM ALUMINUM SULFATE DODECAHYDRATE IN WATER AT 25-DEGREES-C, Journal of solution chemistry, 24(7), 1995, pp. 659-669
Citations number
28
Categorie Soggetti
Chemistry Physical
Journal title
Journal of solution chemistry → ACNP
ISSN journal
00959782
Volume
24
Issue
7
Year of publication
1995
Pages
659 - 669
Database
ISI
SICI code
0095-9782(1995)24:7<659:EOSACO>2.0.ZU;2-O
Abstract
Enthalpies of crystallization of NH4Al(SO4)(2) . 12H(2)O from aqueous solutions at 25 degrees C, measured using a calorimetric method and de termined from previously published data on the concentration dependenc e of the enthalpy of solution, are reported. The results are compared with the values obtained from the temperature dependence of solubility and from vapor pressure data by using the Williamson equation. The in tegral and partial molar enthalpies of solution in concentrated and di luted solutions are given.