AN ASSOCIATION MODEL FOR MIXTURES CONTAINING ANY NUMBER OF ALKANES AND ANY NUMBER OF ALCOHOLS - APPLICATION TO ALCOHOL-ALKANE BINARY-SYSTEMS

Citation
Ca. Schmidt et Sw. Campbell, AN ASSOCIATION MODEL FOR MIXTURES CONTAINING ANY NUMBER OF ALKANES AND ANY NUMBER OF ALCOHOLS - APPLICATION TO ALCOHOL-ALKANE BINARY-SYSTEMS, International journal of thermophysics, 16(5), 1995, pp. 1299-1307
Citations number
7
Categorie Soggetti
Physics, Applied","Chemistry Physical
ISSN journal
0195928X
Volume
16
Issue
5
Year of publication
1995
Pages
1299 - 1307
Database
ISI
SICI code
0195-928X(1995)16:5<1299:AAMFMC>2.0.ZU;2-V
Abstract
A previously derived association model for mixtures of any number of a lcohols and alkanes is applied here to alcohol-alkane binary systems. The model contains two adjustable parameters: a self-association const ant for the alcohol and a parameter that reflects physical interaction s. Correlations for the two parameters are presented which allow the m odel to be used as a two-, one-, or zero-parameter model, depending on the amount of experimental data available. All three forms of the mod el provide adequate results for these systems over a fairly wide tempe rature range.