Ca. Schmidt et Sw. Campbell, AN ASSOCIATION MODEL FOR MIXTURES CONTAINING ANY NUMBER OF ALKANES AND ANY NUMBER OF ALCOHOLS - APPLICATION TO ALCOHOL-ALKANE BINARY-SYSTEMS, International journal of thermophysics, 16(5), 1995, pp. 1299-1307
A previously derived association model for mixtures of any number of a
lcohols and alkanes is applied here to alcohol-alkane binary systems.
The model contains two adjustable parameters: a self-association const
ant for the alcohol and a parameter that reflects physical interaction
s. Correlations for the two parameters are presented which allow the m
odel to be used as a two-, one-, or zero-parameter model, depending on
the amount of experimental data available. All three forms of the mod
el provide adequate results for these systems over a fairly wide tempe
rature range.