A growth mode of silver ultrathin films on the V(100) surface was stud
ied by Auger electron spectroscopy, angular resolved ultraviolet photo
electron spectroscopy, X-ray photoelectron spectroscopy, thermal desor
ption spectroscopy, low energy electron diffraction, electron energy l
oss spectroscopy and work function change (w.f.c.) measurements. The f
irst two silver layers grow on a V(100) surface in a layer-by-layer mo
de in a wide temperature range (250-900 K). The atoms of both layers a
re sitting in registry with the substrate mesh producing a bcc (100) o
rdered silver ultrathin film.