The structure of thin layers of boron nitride obtained by low temperat
ure plasma enhanced chemical vapour deposition of borazine as precurso
r has been investigated by X-ray diffraction method. The diffraction p
attern consists of the superposition of the three patterns: from non-c
rystalline turbostrate am-BN, from polycrystalline h-BN and c-BN. The
sizes of intermolecular (nucleus surrounded by ''fringe''), 14.8 Angst
rom, and intramolecular (nucleus), 7.6 Angstrom, formations are evalua
ted from the reflection positions in non-crystalline stare and confirm
ed by calculation. Polycrystalline reflections from h-BN and c-BN are
in accordance with known ones for these modifications.