J. Murota et al., ATOMIC LAYER-BY-LAYER EPITAXY OF SILICON AND GERMANIUM USING FLASH HEATING IN CVD, Journal de physique. IV, 5(C5), 1995, pp. 1101-1108
Atomic layer-by-layer epitaxy control of Si and Ge in flash-heating CV
D using SiH4 and GeH4 gases was investigated. Self-limiting SiH4 react
ion on the Ge surface results in Si atomic-layer formation at substrat
e temperatures below 300 degrees C even without the flash heating. In
the case of Ge growth, by increasing the flash light intensity and the
GeH4 partial pressure, Ge atomic-layer growth on the wet-cleaned Si(1
00) was achieved with a single flash shot at 275 degrees C. Using thes
e growth controls, resonant tunneling diodes of Ge/Si1Ge1(50 Angstrom)
/Ge(50 Angstrom) /Si1Ge1(50 Angstrom)/Ge, in which the Si1Ge1 layers w
ere formed by alternately depositing single atomic-layers of Si and Ge
, were fabricated, and clear negative resistance in the current-voltag
e characteristic was observed at 10 K. The current peaks were expected
to be assigned to a hole resonant tunneling via light-hole bound stat
e in the Ge quantum well. This fact suggests that the diode structure
has abrupt Si1Ge1/Ge interfaces by employing a low-temperature atomic
layer-by-layer growth process below 300 degrees C.