HYDROCARBONS AND CHLOROAROMATICS FROM ANILINES AND N-BUTYL NITRITE

Authors
GIUMANINI AG VERARDO G GORASSINI F STRAZZOLINI P
Citation
Ag. Giumanini et al., HYDROCARBONS AND CHLOROAROMATICS FROM ANILINES AND N-BUTYL NITRITE, Recueil des travaux chimiques des Pays-Bas, 114(7), 1995, pp. 311-315
Citations number
26
Categorie Soggetti
Chemistry
Journal title
Recueil des travaux chimiques des Pays-Bas → ACNP
ISSN journal
01650513
Volume
114
Issue
7
Year of publication
1995
Pages
311 - 315
Database
ISI
SICI code
0165-0513(1995)114:7<311:HACFAA>2.0.ZU;2-U
Abstract
A single reagent, i.e. n-butyl nitrite, can be used to oxidize an arom atic amine, or the corresponding N-methylene derivative, to a diazo co mpound followed by its subsequent reduction to hydrocarbon in a single batch. Alternatively, a chloro derivative can be obtained if carbon t etrachloride is used as the solvent. The reactions appear to be genera l and complete product identification was accomplished.