THE EFFECT OF RADIATION AND METAL-ION ADDITION ON THE CO2 REDUCING REACTION IN IRON-CONTAINING WATER

Citation
N. Fujita et al., THE EFFECT OF RADIATION AND METAL-ION ADDITION ON THE CO2 REDUCING REACTION IN IRON-CONTAINING WATER, Radiation physics and chemistry, 46(3), 1995, pp. 345-352
Citations number
19
Categorie Soggetti
Nuclear Sciences & Tecnology","Chemistry Physical","Physics, Atomic, Molecular & Chemical
ISSN journal
0969806X
Volume
46
Issue
3
Year of publication
1995
Pages
345 - 352
Database
ISI
SICI code
0969-806X(1995)46:3<345:TEORAM>2.0.ZU;2-T
Abstract
The effect of gamma-rays and metal ion additives has been studied usin g solutions suspended with iron powder and saturated with CO2. It is p roved that the products are H-2, CO and seven hydrocarbons composed of less than 4 carbon atoms, and that CO is formed only under irradiatio n, unlike other products. Without gamma-rays, the yield is significant ly reduced by introducing metal ions, whereas an increased yield is co nfirmed under exposure. The result is understood by taking into accoun t the reduction of redox potential.