Pw. Villalta et al., A TEMPERATURE-DEPENDENT KINETICS STUDY OF THE CH3O2-IONIZATION MASS-SPECTROMETRY(NO REACTION USING CHEMICAL), Journal of physical chemistry, 99(34), 1995, pp. 12829-12834
The rate constant of the CH3O2 + NO gas-phase reaction was measured ov
er the temperature range 199-429 K-using chemical ionization mass spec
trometry detection of the CH3O2 reactant. The temperature-dependent ex
pression for the rate constant was determined to be k(T) = (2.8 +/- 0.
5) x 10(-12) exp{(285 +/- 60)/T} cm(3) molecule(-1) s(-1). The 298 K r
ate constant, k = (7.5 +/- 1.3) x 10(-12) cm(3) molecule(-1) s(-1), ag
rees well with previous results.