CADMIUM BIS(ALKYLTHIOLATE) COMPLEXES AS PRECURSORS FOR CADMIUM-SULFIDE - A MILD ROUTE TO HAWLEYITE

Authors
KRAUTER G REES WS
Citation
G. Krauter et Ws. Rees, CADMIUM BIS(ALKYLTHIOLATE) COMPLEXES AS PRECURSORS FOR CADMIUM-SULFIDE - A MILD ROUTE TO HAWLEYITE, Journal of materials chemistry, 5(8), 1995, pp. 1265-1267
Citations number
57
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
5
Issue
8
Year of publication
1995
Pages
1265 - 1267
Database
ISI
SICI code
0959-9428(1995)5:8<1265:CBCAPF>2.0.ZU;2-E
Abstract
The preparation, characterization and thermolysis of Cd(SR)(2) (R = Pr -i, Bu(t), Bz), [Cd(SPri)(2) . 1-methylimidazole] and {[Cd(SBz)(2)](2) . 1-methylimidazole} are reported. The volatile organosulfur reaction co-products were identified as RSR, or its subsequent secondary decom position products. Hawleyite is formed from Cd(SBz)(2) at 300 degrees C, 0.1 atm, 4 h; whereas the other two Cd(SR), examples produce the ex pected Greenockite.