J. Madden et al., RETENTION MODELS IN ION CHROMATOGRAPHY AND THEIR USE IN COMPUTER OPTIMIZATION OF ELUENT COMPOSITION, TrAC. Trends in analytical chemistry, 15(10), 1996, pp. 531-537
Computer optimization of eluent composition in ion chromatography can
be performed using a retention model to predict elution behaviour of s
olutes. Approaches to optimization are outlined and some of the more r
ecently published retention models are discussed in terms of the exper
imental parameters necessary for their implementation and the complexi
ty of calculation necessary to solve the appropriate mathematical rela
tionships in the models.