The deterioration phenomena of roof tiles in model systems, formed fro
m clay minerals and Ca-carbonate component, have been investigated. Th
e systems after a specific thermal treatment were exposed to real atmo
spheric conditions, i.e. to attack of sulphurous acidic rains. The dua
l action, of SO2 and atmospheric humidity, on roofing tiles, supportin
g the destruction phenomena of samples, elucidated the formation of sp
ecific phases: gel of calcium silicate hydrates and crystals of alumin
ate hydrates, cancrinite, scawtite and zeolites. (C) 1997 Elsevier Sci
ence Limited and Techna S.r.l.