M. Wittkop et al., ON THE DEFORMATION OF HARD ELASTIC POLYMERS - APPLICABILITY OF THE COIL-STRAND-TRANSITION MODEL, Acta polymerica, 46(4), 1995, pp. 319-327
The applicability of the coil-strand-transition model to describe the
deformation of hard elastic polymers was studied by deformation and re
laxation tests of hard elastic polyethylene and hard elastic polypropy
lene samples in different liquids. It was found that within the model
the calculated values of the fibril diameter,the contribution of surfa
ce stress and the total stress are in agreement with measurements. The
dominance of energetic contributions to the stress was also confirmed
.