ON THE DEFORMATION OF HARD ELASTIC POLYMERS - APPLICABILITY OF THE COIL-STRAND-TRANSITION MODEL

Citation
M. Wittkop et al., ON THE DEFORMATION OF HARD ELASTIC POLYMERS - APPLICABILITY OF THE COIL-STRAND-TRANSITION MODEL, Acta polymerica, 46(4), 1995, pp. 319-327
Citations number
56
Categorie Soggetti
Polymer Sciences
Journal title
ISSN journal
03237648
Volume
46
Issue
4
Year of publication
1995
Pages
319 - 327
Database
ISI
SICI code
0323-7648(1995)46:4<319:OTDOHE>2.0.ZU;2-O
Abstract
The applicability of the coil-strand-transition model to describe the deformation of hard elastic polymers was studied by deformation and re laxation tests of hard elastic polyethylene and hard elastic polypropy lene samples in different liquids. It was found that within the model the calculated values of the fibril diameter,the contribution of surfa ce stress and the total stress are in agreement with measurements. The dominance of energetic contributions to the stress was also confirmed .