SYNTHESIS OF SYN,SYN ANTI,SYN SYN,ANTI AND ANTI,ANTI STEREOTRIADS FROM A SINGLE PAIR OF ENANTIOMERIC REAGENTS

Authors
MARSHALL JA PERKINS JF WOLF MA
Citation
Ja. Marshall et al., SYNTHESIS OF SYN,SYN ANTI,SYN SYN,ANTI AND ANTI,ANTI STEREOTRIADS FROM A SINGLE PAIR OF ENANTIOMERIC REAGENTS, Journal of organic chemistry, 60(17), 1995, pp. 5556-5559
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of organic chemistry → ACNP
ISSN journal
00223263
Volume
60
Issue
17
Year of publication
1995
Pages
5556 - 5559
Database
ISI
SICI code
0022-3263(1995)60:17<5556:SOSASA>2.0.ZU;2-7
Abstract
The stannanes (S)-1a, (R)-1b, and (S)-1c add to (S)- and (R)-2-methyl- 3-(benzyloxy)propanal ((S)-2 and (R)-2) to afford the syn,syn (BF3 . O Et(2) promotion), syn,anti (MgBr2 . OEt(2) promotion), anti,anti (SnCl 4-derived reagent in CH2Cl2), and anti,syn (SnCl4-derived reagent in h exane) stereotriad adducts 3, 4, 6, and 7.