M. Rapp et al., DEVELOPMENT OF AN ANALYTICAL MICROSYSTEM FOR ORGANIC GAS-DETECTION BASED ON SURFACE-ACOUSTIC-WAVE RESONATORS, Fresenius' journal of analytical chemistry, 352(7-8), 1995, pp. 699-704
Modified Surface Acoustic Wave (SAW) devices can be used as highly sen
sitive detectors for gases: coated with a selective sorptive layer, th
ey serve as a frequency determining element of an oscillator circuit.
To perform a quantitative analysis of organic gas mixtures with polyme
r coatings as sensitive membranes, it is necessary to use an array of
several SAW sensors with sensitivities towards various gaseous compone
nts and a subsequent pattern recognition of the sensor responses. An a
utomatic working, self purging and compact analytical microsystem has
been developed for organic gas detection. As the central component it
contains an array of nine commercially available SAW resonators workin
g at frequency of 433.92 MHz. Eight sensor oscillators, one common ref
erence oscillator for temperature compensation and circuits for freque
ncy mixing are mounted within a compact radial housing (diameter 108 m
m). A selection of polymers has been made to detect a broad variety of
gaseous organic analytes. Of particular interest have been hydrocarbo
ns, halogenated hydrocarbons and aromatic compounds. Initial experimen
ts with these analytes have been carried out to proof the selection an
d to optimize the combination of polymer coatings. With the compact se
nsor configuration a very fast response time in the range of seconds i
s obtained for qualitative determination of the analytes.