The nuclear structure of Gd-145 h,, been investigated via the Cd-114(S
-36,5n) reaction. Three superdeformed bands have been discovered, cons
isting of 17, 16 and 10 transitions, respectively, The first excited s
uperdeformed band shows two band crossings which are assigned to the s
ubsequent alignment of an i(13/2) proton pair and a crossing of the i(
13/2) and i(11/2) neutron orbitals, respectively. Such a double band c
rossing has been observed for the first time. The second excited super
deformed band is assigned as the signature partner of the previous ban
d but shows no band crossing in the observed frequency range. The band
crossing behaviour of the SD bands has been described theoretically.