THE PREPARATION AND CHARACTERIZATION OF MONOMERIC LANTHANIDE TETRAPHENYLPORPHYRIN CRYSTALS, [LN(TPP)ACAC-CENTER-DOT-3TCB-CENTER-DOT-8H(2)O](LN=GD, SM)

Authors
JIANG JZ WEI LL GAO PL GU ZN MACHIDA KI ADACHI GY
Citation
Jz. Jiang et al., THE PREPARATION AND CHARACTERIZATION OF MONOMERIC LANTHANIDE TETRAPHENYLPORPHYRIN CRYSTALS, [LN(TPP)ACAC-CENTER-DOT-3TCB-CENTER-DOT-8H(2)O](LN=GD, SM), Journal of alloys and compounds, 225(1-2), 1995, pp. 363-366
Citations number
10
Categorie Soggetti
Chemistry Physical","Metallurgy & Metallurigical Engineering","Material Science
Journal title
Journal of alloys and compounds → ACNP
ISSN journal
09258388
Volume
225
Issue
1-2
Year of publication
1995
Pages
363 - 366
Database
ISI
SICI code
0925-8388(1995)225:1-2<363:TPACOM>2.0.ZU;2-A
Abstract
Crystals of tetraphenylporphyrinato lanthanoid(III) complexes, [Ln(tpp )acac . 3TCB . 8H(2)O] (Ln=Gd, Sm), were prep ared and isolated by dir ect crystallization of the reaction mixture from solution of toluene:T CB (10:1). Its monomeric composition was characterized on the basis of UV-vis, magnetic circular dichroism (MCD), IR, Raman, H-1 NMR spectra and elemental analysis. Single-crystal lattice parameters were obtain ed by X-ray crystallography of triclinic [Gd(tpp)acac . 8H(2)O . 3TCB] , a = 19.72 Angstrom, b=21.62 Angstrom, c=23.15 Angstrom, alpha=69.64 degrees, beta=81.52 degrees, gamma=83.06 degrees, and V=9048 Angstrom( 3).