L. Garlaschelli et al., THE STRUCTURES OF NEW LANOSTANE TRITERPENES FROM THE FRUITING BODIES OF HEBELOMA-SENESCENS, Journal of natural products, 58(7), 1995, pp. 992-1002
Three new lanostane triterpenes, hebelomic acids B [4], E [5], and F [
6], were isolated from the inedible mushroom Hebeloma senescens. The l
atter two compounds are acyl derivatives of the new triterpene senesce
nsol (12-deoxycrustulinol) [12]. The structures of compounds 4-6, incl
uding the absolute configuration of the 3-hydroxy-3-methylglutaric aci
d moiety, were established on the basis of spectral and chemical evide
nce.