THERMAL-DECOMPOSITION OF ALPHA-(DIFLUOROAMINO)POLYNITROALKANES

Authors
GREBENNIKOV VN NAZIN GM MANELIS GB
Citation
Vn. Grebennikov et al., THERMAL-DECOMPOSITION OF ALPHA-(DIFLUOROAMINO)POLYNITROALKANES, Russian chemical bulletin, 44(4), 1995, pp. 628-630
Citations number
6
Categorie Soggetti
Chemistry
Journal title
Russian chemical bulletin → ACNP
ISSN journal
10665285
Volume
44
Issue
4
Year of publication
1995
Pages
628 - 630
Database
ISI
SICI code
1066-5285(1995)44:4<628:TOA>2.0.ZU;2-2
Abstract
The compounds RC(NO2)(2)NF2 differ little from their nitro analogs, RC (NO2)(3), in stability. They decompose in the gas and liquid phases at identical rates and the decomposition is controlled by cleavage of a C-NO2 bond. For R = NO2, F, and Me the Arrhenius parameters, E (kJ mol (-1)) and log (Als), are: 161.3 and 16.00; 180.2 and 16.20; 168.4 and 16.00, respectively.