NEW 2,3-DIHYDRO-5H-1,4-BENZODIOXEPIN DERIVATIVES - EASY FORMATION ANDX-RAY STRUCTURE DETERMINATION OF A PENTACYCLIC ACETAL CONTAINING A 14-MEMBERED CARBON-OXYGEN RING

Authors
LUCCHESINI F BERTINI V POCCI M DEMUNNO G CRISPINI A
Citation
F. Lucchesini et al., NEW 2,3-DIHYDRO-5H-1,4-BENZODIOXEPIN DERIVATIVES - EASY FORMATION ANDX-RAY STRUCTURE DETERMINATION OF A PENTACYCLIC ACETAL CONTAINING A 14-MEMBERED CARBON-OXYGEN RING, Tetrahedron, 51(35), 1995, pp. 9757-9766
Citations number
15
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
51
Issue
35
Year of publication
1995
Pages
9757 - 9766
Database
ISI
SICI code
0040-4020(1995)51:35<9757:N2D-EF>2.0.ZU;2-N
Abstract
The acid catalyzed acetalization of 2,6-bis(2-hydroxyethoxy)benzaldehy de (4) is studied under various conditions. New 2,3-dihydro-5H-1,4-ben zodioxepin derivatives are prepared and a fourteen-membered tetraoxyge nated macrocycle is obtained in 81% yield without special synthetic ex pedients. The solid state molecular structure of the macrocyclic compo und is determined by single crystal X-ray analysis.