OXYDEHYDROGENATION OF PROPANE ON V2O5 TIC2 CATALYST - KINETIC AND MECHANISTIC ASPECTS/

Catalytic oxydehydrogenation of propane and work function measurements in similar conditions have been performed on V2O5/TiO2 catalyst. The oxidation mechanism C3H8--> k(1) C3H6--> k(2) COx + H2O has been kinet ically modelled which permits theoretical evolution of the selectivity as a function of the conversion, for various ratios of K = k(1)/k(2). A good correlation is obtained between the experimental and theoretic al curves, validating the kinetic modelling. The value obtained for K is << 1, so the reactivity of propene is much higher than that of prop ane and justifies the observed yield limitation. Moreover, the rate-de termining step of propane ODH reaction as well as of propene oxidation is attributed to the attack of the oxidized site by the hydrocarbon. The value of K, which depends on the type of catalyst may be used to e valuate the selectivity to propene and for classification of oxydehydr ogenation catalysts. The work function measurements give the nature an d charge of the various oxygen species (O-2(-), O-, O2-) involved in t he reaction, and O2- is found to react with propane.