Wd. Vilar et al., CHARACTERIZATION OF HYDROXYL-TERMINATED POLYBUTADIENE .3. COMPARISON BETWEEN CONVENTIONAL AND LOW-MOLECULAR-WEIGHT PRODUCTS, Polymer bulletin, 35(4), 1995, pp. 481-488
A comparison between the molecular structure of conventional and low m
olecular weight hydroxyl terminated polybutadienes (HTPBs) is presente
d. The conventional HTPB samples were R45M, R45HT (Atochem), Liquiflex
P and H (Petroflex, Brazil), and the low molecular weight ones were R
20LM (Atochem) and two laboratory synthesized materials. The structura
l differences found were attributed to dissimilarities in fabrication
processes for each type of HTPB. Some mechanistic pathways for the pol
ymerization are suggested.