INVESTIGATION OF THE CR3+ SITES IN SRLAGAO4 CRYSTAL

Citation
W. Rybaromanowski et al., INVESTIGATION OF THE CR3+ SITES IN SRLAGAO4 CRYSTAL, Chemical physics letters, 242(6), 1995, pp. 623-626
Citations number
7
Categorie Soggetti
Physics, Atomic, Molecular & Chemical
Journal title
ISSN journal
00092614
Volume
242
Issue
6
Year of publication
1995
Pages
623 - 626
Database
ISI
SICI code
0009-2614(1995)242:6<623:IOTCSI>2.0.ZU;2-3
Abstract
A single crystal of chromium doped SrLaGaO4 has been grown by the Czoc hralski method. The Cr3+ sites have been indentified on the basis of t ime-resolved luminescence spectra and luminescence decay curves record ed in the 5-300 K temperature region. One Cr3+ site in CrO6 octahedra distorted by random distribution of Sr2+ and La3+ ions over sites with C-4v symmetry is indicated by structural investigations. Instead, thr ee distinct sites of Cr3+ ions situated in the low, medium and high cr ystal field occur in the lattice of SrLaGaO4.