THE METHYLENE ADDUCT OF BIS(1,2-DIPHENYL-1,2-ETHYLENEDITHIOLATO)NICKEL(II) - A NICKEL(II) COMPLEX OF CIS-(METHYLENETHIO)STILBENETHIOL WHICHCYCLODIMERIZES TO 0-TETRAPHENYL-1,3,6,8-TETRATHIA-4,9-CYCLODECADIENE

Authors
SAKURADA M SCHLEMPER EO SCHRAUZER GN
Citation
M. Sakurada et al., THE METHYLENE ADDUCT OF BIS(1,2-DIPHENYL-1,2-ETHYLENEDITHIOLATO)NICKEL(II) - A NICKEL(II) COMPLEX OF CIS-(METHYLENETHIO)STILBENETHIOL WHICHCYCLODIMERIZES TO 0-TETRAPHENYL-1,3,6,8-TETRATHIA-4,9-CYCLODECADIENE, Chemistry Letters, (8), 1995, pp. 651-652
Citations number
7
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1995
Pages
651 - 652
Database
ISI
SICI code
0366-7022(1995):8<651:TMAOB>2.0.ZU;2-P
Abstract
The reaction of is(1,2-diphenyl-1,2-ethylenedithiolato)nickel(II), Ni( S(2)C(2)Ph(2))(2), with diazomethane affords a 1:1 methylene adduct, N i[CH2(S(2)C(2)Ph(2))(2)] (2), which is identified as a nickel(II) comp lex of cis-(methylenethio)stilbenethiol (3). Ligand 3 cyclodimerizes, on decomposition of 2 or by reaction of 2 with 2,2'-bipyridyl, to yiel d -tetraphenyl-1,3,6,8-tetrathia-4,9-cyclodecadiene.