THE FIRST TRIGONAL-BIPYRAMIDAL STRUCTURE OF ZINC(II) COMPLEX OF A BLEOMYCIN MODEL

Authors
KUROSAKI H HAYASHI K ISHIKAWA Y GOTO M
Citation
H. Kurosaki et al., THE FIRST TRIGONAL-BIPYRAMIDAL STRUCTURE OF ZINC(II) COMPLEX OF A BLEOMYCIN MODEL, Chemistry Letters, (8), 1995, pp. 691-692
Citations number
10
Categorie Soggetti
Chemistry
Journal title
Chemistry Letters → ACNP
ISSN journal
03667022
Issue
8
Year of publication
1995
Pages
691 - 692
Database
ISI
SICI code
0366-7022(1995):8<691:TFTSOZ>2.0.ZU;2-0
Abstract
A new bleomycin analogue mino)-carbonyl]-6-[((2-amino-2-methylpropyl)a mino) methyl]pyridine, L, was prepared and the coordination mode of L to Zn(II) was characterized in both solution and solid state as a Zn(I I)-bleomycin model complex. With L, Zn-II forms 4-coordinate, tetrahed ral [ZnL](2+) at pH < 6 acid 5-coordinate [ZnH(-1)L](+) at H-p > 8. Th e [ZnH(-1)L]ClO4 . H2O complex has a trigonal-bipyramidal complex stru cture by the X-ray crystal study.