A CONVENIENT SYNTHESIS OF PERFLUOROALKYLATED ENAMINES AND VINYL PHOSPHONATES

Authors
CEN WB NI YH SHEN YC
Citation
Wb. Cen et al., A CONVENIENT SYNTHESIS OF PERFLUOROALKYLATED ENAMINES AND VINYL PHOSPHONATES, Journal of fluorine chemistry, 73(2), 1995, pp. 161-164
Citations number
14
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
73
Issue
2
Year of publication
1995
Pages
161 - 164
Database
ISI
SICI code
0022-1139(1995)73:2<161:ACSOPE>2.0.ZU;2-K
Abstract
The reaction of fluoroalkynes with ammonia and benzylamine gave perflu oroalkylated enamines predominantly as the Z isomer, which were hydrog enated with palladium on carbon to afford perfluoroalkylated beta-amin o acids in good yield. The reaction of fluoroalkynes with diethyl phos phite afforded perfluoroalkylated vinyl phosphonates in moderate yield .