REACTION OF ALCOHOLATES WITH ALKYL 2-PERFLUOROALKYLETHANOATE

Authors
THIEBAUT S GERARDIN C AMOS J SELVE C
Citation
S. Thiebaut et al., REACTION OF ALCOHOLATES WITH ALKYL 2-PERFLUOROALKYLETHANOATE, Journal of fluorine chemistry, 73(2), 1995, pp. 179-184
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
73
Issue
2
Year of publication
1995
Pages
179 - 184
Database
ISI
SICI code
0022-1139(1995)73:2<179:ROAWA2>2.0.ZU;2-1
Abstract
The reaction of alcoholates with esters of perfluoroalkylethanoic acid (I) and 3-perfluoroalkyl-3-fluoro-propenoic acid (II) has been studie d. Formation of ethers of the enol ester III or the acetal IV depends on the stoichiometric conditions used. The formation of the products p roceeds via a Michael-type addition and elimination of fluoride ions f rom the enolate formed as an intermediate.