SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF 1,2,4,6,7,9-HEXAFLUORODIBENZO-P-DIOXIN

Authors
HAFFER U ROTARD W PICKARDT J
Citation
U. Haffer et al., SYNTHESIS AND X-RAY CRYSTAL-STRUCTURE OF 1,2,4,6,7,9-HEXAFLUORODIBENZO-P-DIOXIN, Journal of fluorine chemistry, 73(2), 1995, pp. 265-266
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Journal of fluorine chemistry → ACNP
ISSN journal
00221139
Volume
73
Issue
2
Year of publication
1995
Pages
265 - 266
Database
ISI
SICI code
0022-1139(1995)73:2<265:SAXCO1>2.0.ZU;2-0
Abstract
1,2,4,6,7,9-Hexafluorodibenzo-p-dioxin was synthesized from 2,3,4,6-te trafluorophenol in the presence of sodium-t-butylate. An X-ray structu re analysis has been performed. The molecule is essentially planar and possesses a centre of inversion. The C-C bond distances range from 13 6.3(7) to 138.3(6) pm and the C-F distances from 133.8(5) to 134.5(6) pm. The C-O distances are 137.8(5) and 139.1(6) pm, respectively.