NOVEL SYNTHESIS OF PERFLUORONITROSOALKANE S CNF2N+1NO (N=1,2,3,6)

Citation
K. Ludovici et al., NOVEL SYNTHESIS OF PERFLUORONITROSOALKANE S CNF2N+1NO (N=1,2,3,6), Journal of fluorine chemistry, 73(2), 1995, pp. 273-274
Citations number
13
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
ISSN journal
00221139
Volume
73
Issue
2
Year of publication
1995
Pages
273 - 274
Database
ISI
SICI code
0022-1139(1995)73:2<273:NSOPSC>2.0.ZU;2-V
Abstract
Perfluoronitrosomethane, CF3NO, may be isolated in ca. 50% yield of a reaction mixture of i-C3H7ONO2 with ZnBr(CF3). 2CH(3)CN in the presenc e of aluminium trichloride. Approximately quantitative yields of CnF2n +1NO (n = 1, 2, 3, 6) may be obtained by reacting NOCl with Cd(CnF2n+1 )(2) . glyme. The preparations are described.