AN UNUSUAL STRUCTURE OF THE HYDRATED SODIUM-CHLORIDE COMPLEX OF CRYPTAND-[2.2.2]

Authors
DALLEY NK KRAKOWIAK KE BRADSHAW JS KOU XL IZATT RM
Citation
Nk. Dalley et al., AN UNUSUAL STRUCTURE OF THE HYDRATED SODIUM-CHLORIDE COMPLEX OF CRYPTAND-[2.2.2], Journal of heterocyclic chemistry, 32(4), 1995, pp. 1201-1204
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
32
Issue
4
Year of publication
1995
Pages
1201 - 1204
Database
ISI
SICI code
0022-152X(1995)32:4<1201:AUSOTH>2.0.ZU;2-V
Abstract
The solid state structure of the Na[2.2.2]Cl . 3H(2)O complex has the sodium ion displaced towards one of the cryptand nitrogens and the chl oride and water molecules associated by hydrogen bonds to form a pseud o cube with two chloride ions at opposite corners of the cube and wate r oxygens at the other six corners.