PALLADIUM(0)-CATALYZED ALLYLATION OF 4(5)-SUBSTITUTED IMIDAZOLES, 5(6)-SUBSTITUTED BENZIMIDAZOLES, BENZOTRIAZOLE AND 5(6)-METHYLBENZOTRIAZOLE

Authors
ARNAU N ARREDONDO Y MORENOMANAS M PLEIXATS R VILLARROYA M
Citation
N. Arnau et al., PALLADIUM(0)-CATALYZED ALLYLATION OF 4(5)-SUBSTITUTED IMIDAZOLES, 5(6)-SUBSTITUTED BENZIMIDAZOLES, BENZOTRIAZOLE AND 5(6)-METHYLBENZOTRIAZOLE, Journal of heterocyclic chemistry, 32(4), 1995, pp. 1325-1334
Citations number
54
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
32
Issue
4
Year of publication
1995
Pages
1325 - 1334
Database
ISI
SICI code
0022-152X(1995)32:4<1325:PAO4I5>2.0.ZU;2-S
Abstract
Pd(O)-Catalyzed allylations of 4(5)-nitroimidazole, 1, 2-methyl-4(5)-n itroimidazole, 2, 4(5)-bromoimidazole, 7, 4(5)-methoxyimidazole, 10, 5 (6)-nitrobenzimidazole, 16a, 5(6)-methylbenzimidazole, 16b, benzotriaz ole, 19, and 5(6)-methylbenzotriazole, 22, were studied under several reaction conditions. Nitroimidazoles 1 and 2 were regioselectively all ylated under thermodynamic control, leading to 1-allyl-4-nitro derivat ives.