A CONVENIENT SYNTHESIS OF DIAMINOGLYOXIME AND DIAMINOFURAZAN - USEFULPRECURSORS FOR THE SYNTHESIS OF HIGH-DENSITY ENERGETIC MATERIALS

Authors
GUNASEKARAN A JAYACHANDRAN T BOYER JH TRUDELL ML
Citation
A. Gunasekaran et al., A CONVENIENT SYNTHESIS OF DIAMINOGLYOXIME AND DIAMINOFURAZAN - USEFULPRECURSORS FOR THE SYNTHESIS OF HIGH-DENSITY ENERGETIC MATERIALS, Journal of heterocyclic chemistry, 32(4), 1995, pp. 1405-1407
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of heterocyclic chemistry → ACNP
ISSN journal
0022152X
Volume
32
Issue
4
Year of publication
1995
Pages
1405 - 1407
Database
ISI
SICI code
0022-152X(1995)32:4<1405:ACSODA>2.0.ZU;2-5
Abstract
The reaction of glyoxime (4) and hydroxylamine hydrochloride in aqueou s sodium hydroxide was found to be a safe and inexpensive method for t he preparation of multigram quantities of diaminoglyoxime (5). Potassi um hydroxide mediated dehydration of 5 furnished diaminofurazan (1) in good yield of exceptional purity. The ready availability of 1 and 5 h as facilitated the synthesis of new energetic furazan derivative 8.