Wheat starch was processed in a Baker-Perkins MPF-50D co-rotating twin
-screw extruder, at moisture contents of 25% and 30%, screw speeds of
200 rpm and 300 rpm, feed rate of 30 kg/h, and barrel temperature sett
ings of 100, 120, 140 and 160 degrees C. High performance size exclusi
on chromatography was used to determine the extent of degradation of s
tarch along the extruder channel. Starch degradation was found to take
place in the cooking zone. The first-order mechano-degradation models
, which were developed for a single-screw extruder were extended to th
e twin-screw extruder and improved by including a more accurate descri
ption of gelatinization in the model. The degradation is described by
the equation: chi = 1 - {1 - exp[-k(0) exp (- (Delta E(0) - beta tau)/
(RT)) t]} {1 - exp(-k tau t + B)} where tau is the average shear stres
s, t is the mean residence time of the melt in the active zone of the
screw channel, Delta E(0) is the activation energy, R is the ideal gas
constant, beta is the activation volume, k and k(0) are experimental
constants.