S. Kiil et al., SOLUTION OF TRANSIENT PROBLEMS WITH STEEP GRADIENTS - NOVEL FRONT-TRACKING STRATEGY, Chemical Engineering Science, 50(17), 1995, pp. 2793-2799
A finite element collocation method is formulated for heat and mass tr
ansfer problems involving a steep moving profile of the dependent vari
able. An efficient, parametrically convergent front-tracking procedure
is developed based on a balance on a moving front, and the technique
is applied and tested for the case of a gas-solid non-catalytic reacti
on in a porous solid at high Thiele modulus. Accurate and convergent s
teep profiles are obtained here for Thiele modulus larger than 50 for
the case of slab as well as spherical geometry and found to match the
analytical solution when it exists (such as for slab geometry).