A theoretical basis is presented for the concept of statistical pyrome
tric particle sizing (SPPS) in fluidised bed combustion (FBC). The the
ory makes it possible to obtain the size distributions for observable
particles within given temperature ranges, and thus a statistical esti
mate can be made of the dependence of the temperature of a fuel partic
le on its size during FBC. The SPPS method has been experimentally val
idated by comparison with an independent reference method in a miniatu
re fluidised bed reactor. Graphite spheres were burned one by one and
measurements were taken with a two-colour fiber-optic pyrometer. Pyrom
etric signals were obtained many times during each particle's combusti
on and SPPS was applied to the results. The generation of CO2 was also
recorded and the evolution of the particle's size with time was deter
mined from the CO2 mass balance, assuming shrinking core combustion. T
he average sizes determined by SPPS and also from the CO2 mass balance
were in good agreement for all temperature ranges. The elevation of t
he particle's temperature above that of the bed varied between 20 and
about 200 degrees C. Copyright (C) 1997 by The Combustion Institute