PROPERTIES OF RUBIDIUM NITRATE IN ION-CONDUCTING RBNO3-AL2O3 NANOCOMPOSITES

Citation
Nf. Uvarov et al., PROPERTIES OF RUBIDIUM NITRATE IN ION-CONDUCTING RBNO3-AL2O3 NANOCOMPOSITES, Solid state ionics, 90(1-4), 1996, pp. 201-207
Citations number
26
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
ISSN journal
01672738
Volume
90
Issue
1-4
Year of publication
1996
Pages
201 - 207
Database
ISI
SICI code
0167-2738(1996)90:1-4<201:PORNII>2.0.ZU;2-N
Abstract
Properties of RbNO3 in (1-x)RbNO3-xAl(2)O(3) nanocomposites were studi ed by X-ray powder diffraction, electron diffraction, conductivity mea surements, infrared and Raman spectroscopy, and differential scanning calorimetry. All the experimental techniques used indicate the presenc e of an amorphous RbNO3 layer at the RbNO3-Al2O3 interface in addition to a crystalline RbNO3 phase. Its concentration was determined from t he phase transition enthalpies. The amorphous layer thickness estimate d by means of a simple brick-wall model is 4 nm.