X-RAY STRUCTURAL STUDY OF PH(2)PBCL(2)(DMSO)(2), PH(2)PBCL(2)(HMPT)(2) AND PH(3)PBCL(HMPT)

Authors
YATSENKO AV ASLANOV LA SCHENK H
Citation
Av. Yatsenko et al., X-RAY STRUCTURAL STUDY OF PH(2)PBCL(2)(DMSO)(2), PH(2)PBCL(2)(HMPT)(2) AND PH(3)PBCL(HMPT), Polyhedron, 14(17-18), 1995, pp. 2371-2377
Citations number
45
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
14
Issue
17-18
Year of publication
1995
Pages
2371 - 2377
Database
ISI
SICI code
0277-5387(1995)14:17-18<2371:XSSOPP>2.0.ZU;2-Y
Abstract
An X-ray structural investigation of Ph(2)PbCl(2)(DMSO)(2) (I), Ph(2)P bCl(2)(HMPT)(2) (IT) and Ph(3)PbCl(HMPT) (III) was carried out (DMSO = dimethylsulphoxide, HMPT = hexamethyltriamide phosphoric acid). Compl exes I and II have octahedrally coordinated Pb-IV, but in III the coor dination is trigonal-bipyramidal. Comparison with the analogous tin co mpounds indicates the relative shortening of Pb-C bonds and lengthenin g of Pb-Cl, Pb-N and Pb-O bonds. This phenomenon can be explained in t erms of rehybridization of orbitals of the central atom.