CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLO-TETRAKIS ,2,6,6-TETRAMETHYLHEPTAN-3,5-DIONATE)TITANIUM(IV)] PENTANE ADDUCT

Authors
TROYANOV SI GORBENKO OY
Citation
Si. Troyanov et Oy. Gorbenko, CRYSTAL AND MOLECULAR-STRUCTURE OF CYCLO-TETRAKIS ,2,6,6-TETRAMETHYLHEPTAN-3,5-DIONATE)TITANIUM(IV)] PENTANE ADDUCT, Polyhedron, 16(5), 1997, pp. 777-780
Citations number
18
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
5
Year of publication
1997
Pages
777 - 780
Database
ISI
SICI code
0277-5387(1997)16:5<777:CAMOC,>2.0.ZU;2-N
Abstract
The X-ray crystal structure of titanium(IV) oxo-bis-2,2,6,6-tetramethy lheptan-3,5-dionate, pentane (1:1) adduct has been determined. The tet rameric molecule of [TiO(thd)(2)](4) contains a nearly planar (Ti-O)(4 ) ring with two Ti atoms on a twofold axis. Compared with the dimeric titanium oxo-bis-(acetylacetonate), another type of TiO6 octahedral co nnection takes place, namely through vertices instead of edges. Copyri ght (C) 1996 Elsevier Science Ltd