REGIOSELECTIVE AND DIASTEREOSELECTIVE CONDENSATION OF RESORCARENES WITH PRIMARY AMINES AND FORMALDEHYDE

Authors
ARNECKE R BOHMER V FRIEBE S GEBAUER S KRAUSS GJ THONDORF I VOGT W
Citation
R. Arnecke et al., REGIOSELECTIVE AND DIASTEREOSELECTIVE CONDENSATION OF RESORCARENES WITH PRIMARY AMINES AND FORMALDEHYDE, Tetrahedron letters, 36(35), 1995, pp. 6221-6224
Citations number
8
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
35
Year of publication
1995
Pages
6221 - 6224
Database
ISI
SICI code
0040-4039(1995)36:35<6221:RADCOR>2.0.ZU;2-2
Abstract
Mannich reactions of resorcarenes 1 with chiral amines yield single di astereomeric tetrakis-(benzodihydro-1,3-oxazine) derivatives 2 in high yields (80-90%). Epimerisation of these products occurs in the presen ce of acid.