JUNICEDRANOL, A SESQUITERPENE WITH A NOVEL CARBON SKELETON FROM JUNIPERUS-OXYCEDRUS SSP MACROCARPA

Authors
BARRERO AF ALVAREZMANZANEDA E LARA A
Citation
Af. Barrero et al., JUNICEDRANOL, A SESQUITERPENE WITH A NOVEL CARBON SKELETON FROM JUNIPERUS-OXYCEDRUS SSP MACROCARPA, Tetrahedron letters, 36(35), 1995, pp. 6347-6350
Citations number
7
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron letters → ACNP
ISSN journal
00404039
Volume
36
Issue
35
Year of publication
1995
Pages
6347 - 6350
Database
ISI
SICI code
0040-4039(1995)36:35<6347:JASWAN>2.0.ZU;2-M
Abstract
Junicedranol 1, a sesquiterpene with a novel carbon skeleton, has been isolated from the essential oil of the wood of Juniperus oxycedrus ss p. macrocarpa. The structure was determined by the analysis of 2D NMR spectra to be a 2,2,6,7-teaamethyl-tricycle[5.2.2.0(1.6)]undecane carb on skeleton. Its relative stereochemistry is proposed on the basis of NOESY. The absolute configuration was established by ''Mosher's method ''.