THE CRYSTAL-STRUCTURE AND HYDROLYSIS EQUILIBRIUM OF TRIPHENYL(2-MERCAPTO-1-METHYLIMIDAZOLATO)TIN(IV)

Authors
CASAS JS CASTINEIRAS A MARTINEZ EG GONZALEZ AS SANCHEZ A SORDO J
Citation
Js. Casas et al., THE CRYSTAL-STRUCTURE AND HYDROLYSIS EQUILIBRIUM OF TRIPHENYL(2-MERCAPTO-1-METHYLIMIDAZOLATO)TIN(IV), Polyhedron, 16(5), 1997, pp. 795-800
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
5
Year of publication
1997
Pages
795 - 800
Database
ISI
SICI code
0277-5387(1997)16:5<795:TCAHEO>2.0.ZU;2-T
Abstract
The title compound was prepared from 1-methyl-2(3H)-imidazolinethione and triphenyltin(IV) hydroxide, and its crystal structure was determin ed by X-ray diffraction. The crystal consists of discrete molecules wi th the tin atom coordinated to one carbon atom of each of the three ph enyl groups and to the sulfur atom of the deprotonated ligand. An Sn-N interaction [2.920(3) Angstrom] slightly distorts the tin coordinatio n geometry from that of a perfect tetrahedron. NMR spectroscopy was us ed to study the hydrolysis of this compound in CDCl3. Copyright (C) 19 96 Elsevier Science Ltd