The plasma beam sputtering process was used to prepare CrN and TiN har
d coatings on steel, sapphire and alumina Superstrate substrates at a
temperature of 200 degrees C. The microstructural characteristics, coa
ting morphology, interfacial properties, microhardness and internal, s
tresses were studied for coatings 3 mu m thick. Their oxidation behavi
our in an oxygen flow in a tube furnace was studied at temperatures up
to 600 degrees C for TiN and up to 800 degrees C for CrN coatings. Th
e initial stage of oxidation of TiN and CrN coatings 350 nm thick was
also studied by continuous in-situ electrical resistivity measurements
. This measurement technique offers high reproducibility and accuracy,
so can be used to study oxidation for all types of hard coating, and
especially for new multilayer and duplex coatings. Weight gain measure
ments and Auger electron spectroscopy depth profile analyses of oxidiz
ed stoichiometric CrN coatings showed that oxidation in an oxygen flow
at 800 degrees C for 4 h induced the growth of a stable Cr2O3 film. T
he thickness of this oxide film was only 15% of the total (3 mu m) coa
ting thickness. The surface morphology and small roughness changes - a
s also observed after a long-term test at 800 degrees C for 200 h in o
xygen - indicated that a stoichiometric CrN coating with the measured
properties can be successfully used as a hard and oxidation-resistant
coating in industrial practice, even if the working temperatures are h
igher than 750 degrees C.