Stellite, a Co-base superalloy, exhibits good resistance to wear and c
orrosion. However, this good resistance to wear is sometimes less pron
ounced in some industrial applications such as steel mill equipment. T
he present study was therefore conducted to improve this impoverishmen
t of wear property of Stellite. The maximum hardness after plasma nitr
iding was measured as 1300 HK 0.01, which was facilitated by the forma
tion of CrN. It was found that plasma nitriding at 823 K exhibited rel
atively higher hardness and a thinner compound layer than plasma nitri
ding at 973 K. However, the hardness decreased drastically at 1073 K.
Plasma nitrocarburizing was also applied with the parameters of optimi
zed conditions for plasma nitriding with the addition of methane gas t
o are 80%N-2-H-2 gas mixture. The maximum hardness after plasma nitroc
arburizing was about 1200 HK 0.01 and the thickness of layer was about
30 mu m while it was 8 mu m after plasma nitriding. It was indicated
that carbon was uniformly distributed in the diffusion layer while the
distribution of nitrogen was rich only at the compound layer. Surface
conditions after plasma diffusion treatment are also discussed.