ELECTROCHEMICAL SYNTHESES AND ELECTROCHROMIC PROPERTIES OF CHROMIUM CYANIDE MAGNETIC THIN-FILMS

Electrochemical preparation method and electrochromic properties of th e mixed valence chromium cyanide thin film, which is one of the ferrim agnet with highest critical temperature (T-c) among molecule-based mag nets, were described. The difference in the ability of the ligand subs titution reaction between Cr-II and C-III was utilized to synthesize t he prussian blue analogs. The obtained magnetic material exhibited an excellent electrochromic properties. This indicates the compound has a potential for future display devices, as well as tunable molecule-bas ed magnetic devices.